I don't believe the Square D QO panels support 240v single slot breakers, none of the slots. As said before, you can use what they describe as single pole tandem breakers, which again will free up space in your panel to allow you to use the double slot dual pole or 240v breakers.
Not sure if this search results link will work but if not I simply searched amazon for "QO breakers" and up popped up what I ended up with.
https://www.amazon.com/s/ref=nb_sb_ss_c_1_3?url=search-alias%3Daps&field-keywords=qo+20+amp+breaker&sprefix=qo+%2Caps%2C162&crid=16WC0EXGGJ692
Not sure if this search results link will work but if not I simply searched amazon for "QO breakers" and up popped up what I ended up with.
https://www.amazon.com/s/ref=nb_sb_ss_c_1_3?url=search-alias%3Daps&field-keywords=qo+20+amp+breaker&sprefix=qo+%2Caps%2C162&crid=16WC0EXGGJ692