If you are talking about plugging a solar panel into the Leaf's 12 volt accessory socket to charge the 12 volt battery, that won't work - the socket is Off when the car is Off. You could try a fused, diode-protected (to prevent the panel from draining the battery when it isn't producing power) connection directly to the fuse box, or to the battery (again, fuse-protected is important) to accomplish this. In some cases it might be helpful, but unless you are having 12 volt battery issues, I would advise against it.