I'm not a chemist but from what I read, doping, coating, and re-structuring the anode/cathode can very decidedly change the capabilities of the LiFePo4 battery. For example: A123's nano structured battery provides for a long cycle life, a wide temperature operating range and up to a 23C discharge rate-- a more powerful, longer life, temperature stable battery. Perhaps even an improvement in the density is possible using these processes. The door is wide open for further large format battery development and the company that can scale up production of a more electron dense battery than the current offerings, will lead the parade to the bank.
So, the question is; will Nissan change their Leaf battery? I certainly hope so because their current battery has issues, i.e., temperature and density, fer sure. Yes, they can solve the temperature problem with liquid cooling and they can increase the car's range by "adding light weight," but in my mind the decision to continue without at least a reasonable improvement, about 15% or better, in battery density could be costly for Nissan in the near future.
When GM finally decides the Volt should be a BEV, it will certainly be a competing car for the Leaf. If you remove all the ICE stuff from the Volt, install an A123 battery package and the drive package from the Spark, with it's 400 foot pound motor, you would have a nice EV, especially if they cut costs and build a lesser trim model.