drees said:
Most lithium based batteries have the longest "shelf life" when stored somewhere around half full. Similarly, charging the battery to full or discharging the battery to empty is also hard on the cells. And finally, the faster you charge or discharge the pack, the harder that is on the cells.
This is generally true but really doesn't apply to our EV packs for a number of reasons. So we're clear, let's ignore any battery management hardware and/or software for a moment and just talk about a single raw cell.
LiMn has a max cell voltage a bit over 4.2V and a recommended minimum of 3.0V. Charging above 4.2 and discharging below 3.0 will cause cell damage. Cells do have a max charge and discharge rate - gentler is better. If one is going to store a battery and wants to minimize the damage of time, discharge to ~40% and put the battery in the refrigerator. However...
The car's management system isn't going to allow us to use the top or bottom 10%. This is the difference between the 'ultimate' or 'max' cell capacity and the user capacity. 'Our' user capacity of 100% is the cell's 90% charged, and 'our' empty will be 10% charged. The car won't get us get close to the 4.2V or 3.0V zones where damage will occur and is within the zone of long life already.
Likewise charge/discharge rate. It's very likely that the maximum current we'll be able to draw from the pack will be less than 300A. It's very likely that the Leaf's pack will have two parallel strings of cells. Nissan says we'll have 48 modules of 4 cells in series - 192 cells @ 3.6V nominal is a 691V pack. Not likely. 345V is much more probable. The parallel cells will each take 1/2 the load - 150A max per string. If the Leaf uses AESC's 33Ah cells, and we use a very low-performance 5C discharge rate for the cells, the cells are capable of delivering 165A continuous and twice that for acceleration.
So yes - in general I have to agree completely with what you've suggested. In practice, though, we're not likely to be close to the performance limits of the pack.
Cell capacity will degrade over time even if the cell is charged to 40% and stored for 10 years. To paraphrase Les Brown - if we're going to take the hit anyway, we might as well get some mileage out of the pack!
drees said:
So if you normally only drive 20 miles/day, you'd want to charge the to 60% every day, then trickle charge it back up to 60% for the next day. And that still gives you an extra 40 miles of buffer should you need to go farther. Should you need to go farther the next day, charge it up more accordingly.
I can't point to anything about any of the lithium cells that confirms that this management method would do more than keep one busier than necessary. Since we won't have access to the 'ragged edges' of the battery's comfort zone, then by definition the cell will be comfortable even if we leave the car on the charger 24/7 and only drive 1 mile per day.
I use my road-battery as my rolling test bed for different battery management products. The cells that I've damaged on the bench or on the road have been damaged thru over charge or over discharge. The Leaf just won't let us get get into the danger zone.
drees said:
That does bring up a good question - I wonder if you can set the charge rate on the EVSE? It would be to be able to tell it how fast to charge even if it has the capacity to go from empty-full in 8 hours...
The devices which with I'm aware (AV and Clipper Creek) are pre-set - we cannot adjust the charge rate via the EVSE. We can move from the Level 2 to the Level 1 device. Later on, we might be able to hack the system and turn the charger down from the 'inside'. But the most likely way to limit the charge rate, should a user desire that, is by selecting the EVSE they choose to use - Level 3, 2, or 1.
Andy