I parked my Leaf for 4 days and returned to a dead 12V lead acid battery (and it was only 2 years old). Started reading about everybody having such a good time with LiFePO4 batteries and decided to get one.
I bought an "ECO-WORTHY 12V 30Ah 360 Wh 7.2 lbs LiFePO4" battery on sale at eBay for $125 after tax. That's cheaper than Wal-Mart's $150 lead acid battery, although higher than an Econocraft lead acid for $70 at AutoZone.
The sticker on my 30Ah LiFePO4 says max charge/discharge current 20A/25A, which sucks in my opinion (ACC mode with headlights and stuff turned on can easily exceed 30A). Sticker seems to claim the internal BMS will prevent charging below 0C, which is great if true. Freezing temperatures are rare but may happen once a year here in AZ.
I used a 23 ft length of 16 AWG copper wire to act as a current limiting resistor (about 0.09 ohms) so that when the car pushes 14.2V, it shouldn't exceed the 20A max charging current specification of my LiFePO4 battery. This works and I was still able to start the car with it, but voltage on the car side of the resistor sagged down to 11V briefly during start.
That seemed kind of crappy. I want the car's relays to snap strongly and not bounce, to prolong the life of the contactors. So I added a 15A diode in parallel to the resistor wire, so that the car can take current out of the battery without impedance. This was very satisfactory, no more big voltage sage during car starting. 15A is a little bit small, IMO, but it was the biggest diode I happened to have on hand. I'd recommend going bigger if possible.
My car is working nicely (as long as I don't use ACC mode with lots of stuff turned on), but I did notice the car constantly goes into 14.2V charging mode for 50 seconds (it used to just constantly float at 13.1V for the most part). Since LiFePO4's nominal voltage during the bulk of it's discharge curve is 12.8V, the car is constantly going 14.2V for 50 seconds, 13.1V for a few minutes, eventually sliding down to 12.8V, then repeating.
That seems dumb to me. Ideally, I'd like the car to let the battery voltage float down to 12.5V or more before initiating a recharge cycle. If I buy a really big LiFePO4 12V battery (with higher max charge/discharge current capability), the car should deep discharge the LiFePO4 battery during operation instead of using the high voltage traction battery to power the 12V rail. In my opinion, it should be possible to extend the range of the car a bit if we restrict the car to only recharge the 12V battery while connected to grid power.
Is it possible to take control of the Leaf's DC-DC converter with a CAN bus bridge? I'd be interested in getting one of those (if they ever become in-stock) and doing some firmware hacking to get this done.